Ewald Hofman, an ALM MVP, has written a great series of blog posts on Team Build in Team Foundation Server 2010.  The 2010 release introduces Windows Workflow as the overall orchestrator of the build process.  Ewald walks you through quite a few topics related to this and the other new features.  Check it out!

1. Part 1: Introduction
2. Part 2: Add arguments and variables
3. Part 3: Use more complex arguments
4. Part 4: Create your own activity
5. Part 5: Increase AssemblyVersion
6. Part 6: Use custom type for an argument
7. Part 7: How is the custom assembly found
8. Part 8: Send information to the build log
9. Part 9: Impersonate activities (run under other credentials)
10. Part 10: Include Version Number in the Build Number
11. Part 11: Speed up opening my build process template
12. Part 12: How to debug my custom activities
13. Part 13: Get control over the Build Output
14. Part 14: Execute a PowerShell script
15. Part 15: Fail a build based on the exit code of a console application
16. Part 16: Specify the relative reference path